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1 article(s) from Rodríguez-Padrón, Daily

New bio-nanocomposites based on iron oxides and polysaccharides applied to oxidation and alkylation reactions

Daily Rodríguez-Padrón,
Alina M. Balu,
Antonio A. Romero and
Rafael Luque

Beilstein J. Org. Chem. 2017, 13, 1982–1993, doi:10.3762/bjoc.13.194

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Graphical Abstract

Figure 1: Overview of the preparation of the nanocomposites based on iron oxide and polysaccharide.

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Figure 2: XPS spectra of A: Fe₂O₃-PS4, B: Fe₂O₃-PS4-MNP and C: TiO₂-Fe₂O₃-PS4 nanohybrids.

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Figure 3: A and B: SEM and TEM images of TiO₂-Fe₂O₃-PS4; C and D: SEM and TEM images of Fe₂O₃-PS4. E and F: S...

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Figure 4: DRIFT spectra of A: TiO₂-Fe₂O₃-PS4 and B: Fe₂O₃-PS4-MNP nanohybrids.

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Scheme 1: Oxidation of benzyl alcohol to benzaldehyde.

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Figure 5: Conversion and selectivity of the oxidation of benzyl alcohol for the three catalytic systems.

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Scheme 2: Microwave-assisted alkylation of toluene with benzyl chloride.

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Figure 6: Conversion and selectivity of the microwave-assisted alkylation of toluene for the three catalytic ...

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Scheme 3: Alkylation of toluene with benzyl chloride with conventional heating.

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Figure 7: Conversion and selectivity of the alkylation of toluene with conventional heating for the three cat...

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Figure 8: Reusability of the iron oxide/polysaccharide nanohybrids.

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Published 21 Sep 2017

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